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_toc.yml

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- file: ch03/demo_PIB
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- file: ch03/demo_quantum_waves
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- file: ch03/bonus_quantum_waves
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- file: ch03/fourier_transform
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- file: ch04/index
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sections:
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- file: ch04/note01

ch03/demo_quantum_waves.ipynb

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"interact(plot_wavefunction, t=(0, 10, 0.1), c1=(-1.5, 1.5, 0.1), c2=(-1.5, 1.5, 0.1), n1=(1,5), n2=(1,5))"
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]
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},
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{
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"cell_type": "markdown",
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"metadata": {},
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"source": [
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"### Fourier Transforms"
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]
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},
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{
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"cell_type": "code",
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"execution_count": null,

ch03/fourier_transform.ipynb

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ch03/note05.md

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### Eigenfunctions of Hermitian operators form complete basis set
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The three crucial consequences of Hermitian property of operators
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::::{grid}
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::::
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The three crucial consequences of Hermitian property of operators:
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- **Eigenvalues are real**:
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$$\mid f\rangle = \sum_i c_i \mid \psi_i \rangle$$
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- The last two properties imply that eigenfunctions of Hermitian opeartors play the same role for functions as the unit vectors for vectors. Thus a wavefunction can be expressed in terms of the eigenfunctions of an opearators which can act on the function.
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- The last two properties imply that eigenfunctions of Hermitian opeartors play the same role for functions as the unit vectors for vectors.
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- Thus a wavefunction can be expressed in terms of the eigenfunctions of an opearators which can act on the function.
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### Wave function as a linear superoposition of eigenfunctions
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:::{grid-item-card} Dirac Notation
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$$f\psi(x) = \sum_n c_n \Big(\frac{2}{L}\Big )^{1/2} sin \Big (\frac{n\pi x}{L} \Big )$$
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$$\psi(x) = \sum_n c_n \Big(\frac{2}{L}\Big )^{1/2} sin \Big (\frac{n\pi x}{L} \Big )$$
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$$c_k = \Big(\frac{2}{L}\Big )^{1/2} \int sin \Big (\frac{k\pi x}{L} \Big )\psi(x) dx$$
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- Quantum objects an exist in any supersposition states. For instance an atom can be in a superposition of ground and next excited states with 50% probabilities.
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- Wavefunction must be normalizable
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- From normalization condition imposed on wavfunction we see the true meaning of coeficients in linear superopositions
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$$\mid \psi \rangle=c_1 \mid 1 \rangle+c_2 \mid 2\rangle$$
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$$\psi(x)=\frac{1}{\sqrt{2}}\cdot \Big(\frac{2}{L} \Big )^{1/2}sin\frac{\pi x}{L}+\frac{1}{\sqrt{2}}\cdot \Big(\frac{2}{L} \Big )^{1/2}sin\frac{5\pi x}{L}$$
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This means that when we measure energy we are going to obtain only two values $E_1$ and $E_5$ with equal probabilities $p_1=p_2=(1/\sqrt{2})^2$.
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The average of energy will be given by
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- This means that when we measure energy we are going to obtain only two values $E_1$ and $E_5$ with equal probabilities $p_1=p_2=(1/\sqrt{2})^2$. The average of energy will be given by
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$$\langle E \rangle =p_1 E_1+p_2 E_2 = \frac{1}{2}\frac{1^2 h^2}{8mL^2}+\frac{1}{2}\frac{5^2 h^2}{8mL^2}$$
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$$\mid \psi \rangle \rightarrow \mid \phi_n \rangle$$
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- Differnet eigenvalues are observed doing experiments with probability $\mid c_n \mid^2$
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- In experiments on only observes different eigenvalues with probability given by squared coefficients: $\mid c_n \mid^2$
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- The idea of a quantum system randomly collapsing into distinct and mutuallye esclusive states has trubled many physicsis, who were at the frontiers of development of quantum mechanics.
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- Orthogonality of eigenfunctions implies mutual exclusivity of system being in state 1 vs state 2
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- **Orthogonal of eigenfunctions** means **mutually exclusive** states. E.g system can only be in either state 1 or 2 but not both.
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$$\langle \phi_1 \mid \phi_2 \rangle=0$$
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