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Parameters.jl
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Parameters.jl
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(
N = 400, # Subintervals in perovskite layer, resulting in N+1 Grid points
# Physical parameters
ε₀ = 8.854187817e-12u"F/m",# Permitivity of free space
q = 1.6021766209e-19u"C", # Elemntary charge of a proton
kB = 8.61733035e-5u"eV/K", # Bolzmann konstant
# Perovskite parameters
b = 400e-9u"m", # Perovskite Layer thickness
ε = 24.1, # Perovskite permitivity
Ec = -3.7u"eV", # Perovskite Conduction band energy
Ev = -5.3u"eV", # Perovskite Valence band energy
dₚ = 0u"m^-3", # Peroviskite doping concentration
Dₙ = 1.7e-4u"m^2/s", # Perovskite electron diffusion coefficient
Dₚ = 1.7e-4u"m^2/s", # Perovskite hole diffusion coefficient
mₑ = 0.2, # Perovskite electron mass
mₕ = 0.2, # Perovskite hole mass
# Ion Parameters
N₀ = 1.6e24u"m^-3", # Typical density of ion vacancys
Dᵢ₀ = 6.5e-8u"m^2/s", # Diffusion constant
Eᵢₐ = 0.58 * u"eV", # Ativation energy of vacancy diffusion
freeze_ions = false,
# Environment Parameters
T = 300u"K", # Temperature
α = 1.3e7u"1/m", # Perovskite absorption coefficient
Fₚₕ = 1.4e21u"m^-2*s^-1", # 1 Sun photonflux
dir = 1, # Light trough 1 -> ETL, -1 -> HTL
light = pulse(tₑ=1.0, w=2.), # Light(t) function [Sun]
V = t -> 0, # Voltage(t) function [V]
Rₛₕ = 1e6u"V/A*m^2", # Shunt resistance
Rₛ = 1e-4u"V/A*m^2", # Series resistance
# Recombination Parameters
τₙ = 3e-7u"s", # electron pseudo lifetime
τₚ = 3e-7u"s", # hole pseudo lifetime
k₂ = 3.22e-17u"m^3/s", # second order rate constant
# Interface Recombination
k₂ₑ = 0u"m^4/s", # ETL/perovskite bimolecular recombination rate
k₂ₕ = 0u"m^4/s", # perovskite/HTL bimolecular recombination rate
vₙₑ = 0u"m/s", # electron recombination velocity for SHR/ETL
vₚₑ = 0u"m/s", # hole recombination velocity for SHR/ETL
vₙₕ = 0u"m/s", # electron recombination velocity for SHR/HTL
vₚₕ = 0u"m/s", # hole recombination velocity for SHR/HTL
# ELT Parameters
dₑ = 1e18u"cm^-3", # ETL effective doping density
mcₑ = 1.5, # ETL electron mass
Ecₑ = -4.0 * u"eV", # ETL conduction band energy
bₑ = 100e-9u"m", # ETL width
εₑᵣ = 3, # ETL permitivity
Dₑ = 1e-7u"m^2/s", # ETL electron diffusion coefficient
# HTL Parameters
dₕ = 1e18u"cm^-3", # HTL effective doping density
mvₕ = 12, # HTL hole mass
Evₕ = -5 * u"eV", # HTL valence band energy
bₕ = 100e-9u"m", # HTL width
εₕᵣ = 3, # HTL permitivity
Dₕ = 1e-7u"m^2/s", # HTL electron diffusion coefficient
)