Skip to content

Commit

Permalink
'update p2 operators'
Browse files Browse the repository at this point in the history
  • Loading branch information
DPotoyan authored Oct 11, 2024
1 parent d74b111 commit f944b42
Showing 1 changed file with 50 additions and 29 deletions.
79 changes: 50 additions & 29 deletions ch03/note04.md
Original file line number Diff line number Diff line change
Expand Up @@ -10,64 +10,85 @@
- Commuting operators share eignefunctions, non-commuiting operators have different eigenfunctions.
:::

### Operators: A reminder
Certainly! Here’s the revised version using single dollar signs for inline equations:

Operators are denoted by a hat symbol which implies that they encode a mathematical operations that can be carried out on functions. For example, the quantum mechanical momentum operator is:
---

$${\hat{p}_x = -i\hbar\frac{d}{dx}}$$
### Operators: A Reminder

- When this operates on a function, it does the following: differentiate the function with respect to $x$ and then multiply the result from by $-i\hbar$.
In quantum mechanics, **operators** represent physical observables and are denoted by a hat symbol ($\hat{}$), which indicates a mathematical operation on functions.

- The quantum mechanical momentum operator of position is:
- For example, the momentum operator is differentiating the function with respect to $x$, then multiplies the result by $-i\hbar$.

$$\hat{x} = x$$
$$
\hat{p}_x = -i\hbar\frac{d}{dx}
$$

- When this operates on a function, it does the following: multiply function by x.
When this operates on a function, it

- The position operator simply multiplies the function by $x$.

### Linearity of operators: A reminder
$$
\hat{x} = x
$$

Operators in quantum mechanics are *linear*, which means that they fulfill the following rules:

$${\hat{A}\left(\psi_1 + \psi_2\right) = \hat{A}\psi_1 + \hat{A}\psi_2}$$
### Linearity of Operators

$${\hat{A}\left(c\psi\right) = c\hat{A}\psi}$$


### Exepctation expression: A reminder

- **Expectation of an bservable** Operators are used to compute average quantities called expectations for the corresponding quantity. E.g average energy, momentum, position.
- Operators in quantum mechanics are **linear**, meaning they satisfy:

$$
{\left < {A}\right> = \int\psi^*\hat{A}\psi d\tau}
\hat{A}(\psi_1 + \psi_2) = \hat{A}\psi_1 + \hat{A}\psi_2
$$

- **Special case when wavefunction $\psi$ is an eigenfunction of an operator $\hat{A}$**

$$
{\hat{A}\psi = a\psi \Rightarrow \left<{A}\right>=\int\psi^*\underbrace{\hat{A}\psi}_{a\psi} d\tau = a\underbrace{\int\psi^*\psi d\tau}_{=1} = a}
\hat{A}(c\psi) = c\hat{A}\psi
$$

- Where $c$ is a constant, and $\psi_1$, $\psi_2$, and $\psi$ are wavefunctions.
- $\hat{x}$, $\hat{p_x}$, $\hat{H}$ all satisfy this property

### Commutations of operators

- From linear algebra we know that order of matrix multiplicaiton matters and that $AB\neq BA$ for two matrices $A$ and B$

- Thus we also ecpect $\hat{A}\hat{B} \neq \hat{B}\hat{A}$ for two operators acting on some function:
### Expectation Value: A Reminder

$$
{\hat{A}\hat{B}f = \hat{A}\left(\hat{B}f\right)}
$$
- The **expectation value** of an observable $\hat{A}$, which gives the average outcome of measurements, is computed as:

$$
\langle A \rangle = \int \psi^* \hat{A} \psi \, d\tau
$$

- **Special Case**: If the wavefunction $\psi$ is an eigenfunction of the operator $\hat{A}$, with eigenvalue $a$:

$$
\hat{A}\psi = a\psi
$$

Then the expectation value simplifies to:

$$
\langle A \rangle = \int \psi^* a \psi \, d\tau = a \int \psi^*\psi \, d\tau = a
$$

Since $\int \psi^*\psi \, d\tau = 1$ (normalization), the expectation value is simply the eigenvalue $a$.



### Commutations of operators

- From linear algebra we know that order of matrix multiplicaiton matters and that $AB\neq BA$ for two matrices $A$ and $B$

- **The commutator of two operators $[\hat{A}, \hat{B}]$** is defined as:
- Thus we generally ecpect $\hat{A}\hat{B} \neq \hat{B}\hat{A}$.
- We can quantify relationship between two operators by computing the **Commutator**:

:::{admonition} **Commutator of operators $\hat{A}$ and $\hat{B}$**
:::{admonition} **Commutator $\hat{A}$ and $\hat{B}$**
:class: important

$${\left[\hat{A},\hat{B}\right]f = \left(\hat{A}\hat{B} - \hat{B}\hat{A}\right)f}$$
:::

- If the commutator of $\hat{A}$ and $\hat{B}$ is zero, it means that their order in multiplication (or the operation order, in other words) may be changed. If the commutator is non-zero, the order may not be changed.
- If the commutator is zero, it means that order in multiplication of operators or matrices can be changed.
- If the commutator is non-zero, the order matters and can not be changed!


:::{admonition} **Example**
Expand Down

0 comments on commit f944b42

Please sign in to comment.